Use of sugarcane bagasse in natura to removal remazol red dye
DOI:
https://doi.org/10.35699/2447-6218.2021.35603Keywords:
Adsorption, Biomass, Synthetic dyeAbstract
In the present article, the feasibility of sugarcane bagasse for the treatment of a synthetic solution of Remazol Vermelho was investigated. For this, a 2² factorial design was performed by varying the pH and mass of the biosorbent in response to the adsorption efficiency, and it was verified that the best adsorption conditions are in acidic pH and lower material mass values. The characterization of the biosorbent was carried out by the pH of the point of zero charge point (PZC), where it was observed that the value was close to 6.00. Infrared spectroscopy (FTIR) data showed the presence of characteristic groups of organic matter and scanning electron microscopy (SEM) showed that the material surface is irregular and porous. A kinetic study was carried out to determine the adsorption mechanism, where the experimental data fit the pseudo-second order model, which indicates that the adsorption occurs by chemosorption. The decontamination percentage reached the value of 72.44% (9.08 ± 0.008 mg g-1) in 30 minutes. In the isotherm study, the experimental data fit the Freundlich model, which indicates a heterogeneous surface. The fixed bed results showed values of 40.63% removal efficiency and 71.38% of column saturation. Therefore, the sugarcane bagasse showed good adsorption capacity for the dye Remazol Vermelho.
Downloads
References
Anizelli, P. R.; Baú, J. P. T.; Gomes, F. P.; Costa, A. C. S.; Carndeiro, C. E. A.; Zaia, C. T. B.; Zaia, D. A. M. 2015. A Prebiotic Chemistry Experiment on the Adsorption of Nucleic Acids Bases onto a Natural Zeolite. Origins of Life and Evolution of Biosphere, 45: 289-306. DOI: https://doi.org/10.1007/s11084-015-9401-1.
Araujo, a. L. P.; noqueira, i. L.; silva, m. G. C.; gimenes, m. L.; barros, m. A. S. D. 2013. Adsorção de Ni2+ e Zn2+ em argila calcinada: estudo de equilíbrio em coluna de leito fixo. Cerâmica, 59: 382-388. DOI: https://doi.org/10.1590/S0366-69132013000300006.
Balarak, D.; Jaafari, J.; Hassani, G.; Mahdavi, W.; Tyagi, I.; Agarwal, S.; Gupta, V. K. 2015. The use of low-cost adsorbent (Canola residues) for the adsorption of methylene blue from aqueous solution: Isotherm, kinetic and thermodynamic studies. Journal of Colloid and Interface Science, 7: 16-19. DOI: https://doi.org/10.1016/j.colcom.2015.11.004.
Barros Neto, B.; Scarminio, I. S.; Bruns, R. E. 2010. Como fazer experimentos: pesquisa e desenvolvimento na ciência e na indústria. Bookman, Porto Alegre, RS, Brasil.
Battistelle, R. A. G., Marcilio, C.; Lahr, F. A. C. 2009. Emprego do bagaço da cana-de-açúcar (Saccharum officinarum) e das folhas caulinares do bambu da espécie Dendrocalamus giganteus na produção de chapas de partículas. Minerva, 5: 297-305. Disponível em: http://www.fipai.org.br/Minerva 05(03) 09.pdf.
Catanho, M.; Malpassa, G. R. P.; Motheo, A. J. 2006. Avaliação dos tratamentos eletroquímico e fotoeletroquímico na degradação de corantes têxteis. Química Nova, 29: 983-989. DOI: https://doi.org/10.1590/S0100-40422006000500018.
Cerqueira, D. A., Guimes, R. V.; Carvalho, R. A.; Valente, A. J. M. 2010. Caracterização de acetato de celulose obtido a partir do bagaço de cana-de-açúcar por 1H-RMN. Polímeros, 20: 85-91. DOI: https://doi.org/10.1590/S0104-14282010005000017.
Costa J. A. S.; Paranhos, C. M. 2019. Evaluation of rice husk ash in adsorption of Remazol Red dye from aqueous media. SN Applied Sciences, 1: 1-8. DOI: https://doi.org/10.1007/s42452-019-0436-1.
Geankopolis, C. J. 1993. Transport Processes and Separation Process Principles, 3ª ed, Prentice-Hall international, New Jersey, USA.
Guaratini, C. C. I.; Zanoni, M. V. B. 2000. Corantes têxteis. Química Nova, 23: 71 - 78. DOI: https://doi.org/10.1590/S0100-40422000000100013.
Gupta, V. K.; Ali, I. 2000. Utilisation of bagasse fly ash (a sugar industry waste) for the removal of copper and zinc from wastewater., Seperation and Purification Technology, 18: 131-140. DOI: https://doi.org/10.1016/S1383-5866(99)00058-1.
Hao. X., Quack, L.; Korah, J., Spieker, W. A.; Regalbuto, J. R. 2004. The control of platinum impregnation by PZC alteration of oxides and carbon. Journal of Molecular Catalysis A: Chemical, 219: 97-107. DOI: https://doi.org/10.1016/j.molcata.2004.04.026.
Ho, S. Y.; Mckay, G. 2000. The kinetics of sorption of divalent metal ions onto sphagnum moss peat. Water Research, 34: 735-742. DOI: http://dx.doi.org/10.1016/S0043-1354(99)00232-8.
Kunz, A.; Peralta-Zamora, P.; S. G. Moraes, S. G.; N. Dúran, N. 2002. Novas tendências no tratamento de efluentes têxteis. Química Nova, 25: 78-82. DOI: https://doi.org/10.1590/S0100-40422002000100014.
Longhinotti, E.; Furlan, L.; Laanjeira, M. C. M.; Fávere, V. T. 1996. Adsorção de azul de metileno e croconato amarelo pelo biopolímero quitina. Química Nova, 19: 221-224. Disponível em http://static.sites.sbq.org.br/quimicanova.sbq.org.br/pdf/Vol19No3_221_v19_n3_01.pdf.
Lopes, W. A.; Fascio, M. 2004. Esquema para interpretação de espectros de substâncias orgânicas na região do infravermelho. Química Nova, 27: 670-673. DOI: https://doi.org/10.1590/S0100-40422004000400025.
Magdalena, C. P.; Fungaro, D. A.; Cunico, P. 2011. Adsorção de azo corante reativo utilizando material zeolítico: tempo de contato, pH, temperatura e efeito de sais. Periódico Tchê Química, 9: 48-59. Disponível em: https://www.ipen.br/biblioteca/2012/17858.
Mimura, A. M. S., Vieira, T. V. A.; Martelli, P. B.; Gorgulho, H. F. 2010. Aplicação da casca de arroz na adsorção dos íons Cu2+, Al3+, Ni2+ e Zn2+, Química. Nova, 33: 1279-1284. DOI: https://doi.org/10.1590/S0100-40422010000600012.
Montagner, C, C., Vidal, C.; Acayaba, R. D. 2017. Contaminantes Emergentes em matrizes aquáticas do Brasil: cenário atual e aspectos analíticos, ecotoxicológicos e regulatórios. Química Nova, 40: 1094-1010. DOI: http://dx.doi.org/10.21577/0100-4042.20170091.
Monteiro, M. S.; Farias, R. F.; Chaves, J. A. P.; Santana, S. A.; Silva, H. A. S.; Bezerra, C. W. B. 2017. Wood (Bagassa guianensis Aubl) and green coconut mesocarp (cocos nucifera) residues as textile dye removers (Remazol Red and Remazol Brilliant Violet). Journal of Environmental management, 204: 23-30. DOI: https://doi.org/10.1016/j.jenvman.2017.08.033.
Moussavi, G.; Khosravi, R. 2010. Removal of cyanide from wastewater by adsorption onto pistachio hull wastes: Parametric experiments, kinetics and equilibrium analysis. Journal of Hazardous Materials, 183: 724-730. DOI: https://doi.org/10.1016/j.jhazmat.2010.07.086.
Nascimento, R. F.; Lima, A. C. A.; Vidal, C. B.; Melo, D. Q.; Raulino, G. S. C. 2014. Adsorção: aspectos teóricos e aplicações ambientais. Imprensa Universitária, Fortaleza, CE, Brasil.
Oliveira, L. S.; Franca, A. S.; Alvesl, T. M.; Rocha, S. D. F. 2008. Evaluation of untreated coffee husks as potential biosorbents for treatment of dye contaminated waters. Journal of Hazardous Materials, 155: 507-512. DOI: https://doi.org/10.1016/j.jhazmat.2007.11.093.
Pereira, R. C., Anizelli, P. R.; Di Mauro E.; Valezi, D. F.; Costa, A. C. S.; Zaia, C. T. B.; Zaia, D. A. M. 2019. The effect of pH and ionic strength on the adsorption of glyphosate onto ferrihydrite. Geochemical Transactions, 20: 1-14. DOI: https://doi.org/10.1186/s12932-019-0063-1.
Rao, M., Parwate, A. V.; Bhole, A. G. 2002. Removal of Cr6+ and Ni2+ from aqueous solution using bagasse and fly ash. Waste Management, 22: 821-830. DOI: https://doi.org/10.1016/S0956-053X(02)00011-9.
Rauf, M.A.; Marzouki, N.; Körbahti, B. K. 2008. Photolytic decolorization of Rose Bengal by UV/H2O2 and data optimization using response surface method. Journal of Hazardous Materials, 159: 602-609. DOI: https://doi.org/10.1016/j.jhazmat.2008.02.098.
Rocha, O. R.; Do Nascimento, G. E.; Campos, N. F.; Silva, V. L.; Duarte, M. M. M. B. 2002. Avaliação do processo adsortivo utilizando mesocarpo de coco verde para remoção do corante cinza reativo BF-2R. Química Nova, 35: 1369-1374. DOI: http://dx.doi.org/10.1590/S0100-40422012000700016.
Rouquerol, J., Avnir, D.; Fairbridge, C. W.; Everett, D. H.; Haynes, J. M.; Pernicone, N.; Ramsay, J. D. F.; Sing, K. S. W.; Unger, K. K. 1994. Recommendations for the characterization of porous solids (Technical Report). Pure and Applied Chemistry, 66: 1739-1758. DOI: http://dx.doi.org/10.1351/pac199466081739.
Seixas, F. L.; Gimenes, M.L.; Fernandes-Machado, N. R. C. 2016. Tratamento da vinhaça por adsorção em carvão de bagaço de cana-de-açúcar. Química Nova, 39: 172-179. DOI: http://dx.doi.org/10.5935/0100-4042.20160013.
Sekar, M.; Sakthi, V.; Rengaraj, S. 2004. Kinetics and equilibrium adsorption study of lead(II) onto activated carbon prepared from coconut shell. Journal of Colloid and Interface Science, 279: 307-313. DOI: https://doi.org/10.1016/j.jcis.2004.06.042.
Shen, Z.; Chen, J. F.; Zou, H. K.; Yun, J. 2004. Dispersion of nanosized aqueous suspensions of barium titanate with ammonium polyacrylate. Journal of Colloid and Interface Science, 275: 158-164. DOI: https://doi.org/10.1016/j.jcis.2003.12.025.
Somorjai, G. A., Li, Y. 2010. Introduction to surface chemistry and catalysis, 2º ed, John Wiley & Sons, New York, NY, USA.
Somsesta, N.; Sricharoenchaikul, V.; Aht-Ong, D. 2020. Adsorption removal of methylene blue onto activated carbon/cellulose biocomposite films: Equilibrium and kinetic studies. Materials and Chemistry and Physics, 240: 1-14. DOI: https://doi.org/10.1016/j.matchemphys.2019.122221.
Souza, K. C.; Antunes, M. L. P.; Conceição, F. T. 2013. Adsorção de corante reativo azul 19 em solução aquosa por lama vermelha tratada quimicamente com peróxido de hidrogênio. Química Nova: 651 - 656. DOI: https://doi.org/10.1590/S0100-40422013000500007.
Vieira, A. P.; Santana, S. A. A.; Bezerra, C. W. B.; Silva, H. A. S.; Chaves, J. A. P.; De Melo, J. C. P.; Da Silva Filho, E. C.; Airolodi, C. 2011. Epicarp and mesocarpo of Babassu (Orbignya speciosa): Characterization and application in copper phtalocyanine dye removal. Journal of Brazilian Chemical Society, 22: 21-29. DOI: https://dx.doi.org/10.1590/S0103-50532011000100003.
Vučrović, V. M.; Razmovski, R. N.; Tekic, M. N. 2012. Methylene blue (cationic dye) adsorption onto sugar beet pulp: Equilibrium isotherm and kinetic studies. Journal of Taiwan Institute Chemical Engineers, 43: 108-111. DOI: https://doi.org/10.1016/j.jtice.2011.06.008.
Published
How to Cite
Issue
Section
License
Copyright (c) 2021 Agrarian Sciences Journal
This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License.
Authors who publish in this journal agree to the following terms:
The Copyright for articles published in this journal follow authorship. The articles are open access, with their own attributions, in educational and non-commercial applications.
The journal reserves the right to make regulatory, orthographic and grammatical changes in the originals, with the aim of maintaining the standard language and the credibility of the vehicle. It will respect, however, the writing style of the authors.
Changes, corrections or suggestions of conceptual order will be forwarded to the authors, when necessary. In such cases, the articles, once appropriate, should be submitted for further consideration.
The opinions issued by the authors of the articles are their sole responsibility.
Agrarian Science Journal is licensed under a 